Allcocks at the IRC Rubber Convention 2014 – Manchester

As we blogged at the time, we attended and manned a stand at the IOM3’s Rubber Convention this year in Manchester. We enjoyed meeting many people from the rubber industry as well as those researching the next big developments for rubber.

Andy Rushton and our stand at the IRC Rubber Convention 2014

Over the two days of the convention (14th and 15th May) we gave out two copies of a history of Manchester in photographs. The first was won by Ms Karin Janet Stein Brito (see picture below) of the Polymer Technology Centre – SENAI in Brazil, whilst the second was won by Mr Bill Adam of Adam Polymer in the UK.

We look forward to the next conference and hope to spread the word of Rubber Reclaim and Rubber Crumb such as their benefits in formulation and myriad uses.

New Year 2014

Hi Everybody,

Just a line to say Happy New Year to all our readers, suppliers and customers.

Best Wishes from all the staff.

Please note our staffing changes:-

Arthur Brookes has now left our employ, and we all wish him the best in his well earned retirement.

Keith Devine has now fully taken over Arthur’s duties, and you should now contact him for all your crumb, granule and recycling requirements.

Sadly, Luke Gilbert will be leaving us at the end of January. He is going travelling in Australia, New Zealand and South East Asia. It’s alright for some !! He will be sorely missed.  A replacement will be put in place as soon as possible.

Red/Brown & Green FKM Crumb Available

Red/Brown and Green FKM Crumb

Red/Brown and Green FKM Crumb

J. Allcock & Sons’ now have the ability to provide an extra 11 tonnes of Red/Brown FKM Crumb and 4 tonnes of Green FKM crumb per month.

Cured FKM scrap is sent to our facilities on a monthly basis and we granulate and “crumb” this FKM scrap to  72′s and 120′s mesh particle size. These particle sizes are not averages, so when we say 120′s Green FKM Crumb, we mean the biggest particle you will find will be 120′s mesh!

We always ask the customers we visit: What’s the cost of testing FKM Crumb in your compound? Compare that amount, to the amount you will be saving if tests came back positive and you started using it…

If you are interested in trialling some of the above crumb, please contact us at ja@allcocks.co.uk or +44 (0) 1612237181.

Alternatively, if you are unsure about using a different FKM compounded crumb in your own FKM compound, why not speak to us about “crumbing” some of your scrap and J. Allcock & Sons’ sending it back to you?

Differences between Size Reduction, Reclaiming and Devulcanisation, in the recycling of rubber.

Differences between Size Reduction, Reclaiming and Devulcanisation in the recycling of rubber.

We have consistently found that the rubber industry confuses itself when discussing recycled rubber. Information has started to become lost and miss-translated; people have stopped collaborating and sharing their knowledge. The purpose of this blog post is to hopefully clear up the difference between the three types; size reduction, reclaiming and devulcanisation. I have already written about both size reduction and reclaiming processes and their advantages, but feel a post about the differences between all three at once,  is worth my time.

First of all, let’s quickly discuss each process:

Size Reduction

Recycled rubber has now become the term most associated with size reduction recycling. This is due to the fact that there has been no chemical process involved in the recycling process. It has been, exactly as named, “Reduced in size”.

There are 3 main types of size reduction recycling; Ambient Grinding, Cryogenic and Wet Paste.

  1. Ambient grinding is grinding/tearing the rubber to the small sizes at room temperature. This is our preferred recycling technique as we firmly believe it gives not only the most economical sized reduced rubber but also the most reusable (due to its shape giving the largest surface area).
  2. Cryogenic is the freezing of scrap rubber using liquid Nitrogen and reducing the size literally by smashing it to pieces. This is less economical due to the amount of liquid nitrogen used per kilo of scrap rubber (1:1 Ratio). The final shape also gives a much smaller surface area as it has flat surfaces, this means less rubber can lock/bond into the rubber compound.
  3. Wet Paste is another grinding technique. This is where the rubber is ground while in water. This can produce finer particles than ambient grinding due to the rubber being in cooled down by the water. Unfortunately this technique is not very economical because the ground rubber almost has an affinity to the water and drying the recycled rubber is extremely hard and costly.

Rubber Reclaim

This is where people start to get confused. Reclaim, Rubber Reclaim, Reclaimed Rubber, as stated is a much more complicated form of recycled rubber, it has been put under a chemical process. In fact, it has been put under a complex thermochemical and mechanical process.

Rubber is first reduced in size and then mixed with oils/reclaiming agents and heat. Without getting into too much detail, this process shortens the polymer chain.

Notes:

  • During the reclaim process small amounts of sulphur cross links may be broken – but not enough to claim it as devulcanisation.
  • For rubbers, such as Nitrile (NBR) which has high chemical and heat resistance, reclaim is not yet possible.

Devulcanisation

Devulcanisation is the rarest of rubber recycling, but probably has the biggest potential. It is the breaking of the sulphur cross links. Breaking these sulphur cross links means that the resulting recycled rubber is almost exactly like the starting rubber compound. The recycled rubber will contain up to 90% of the original properties. This would make it the easiest recycled rubber to reuse.

Unfortunately breaking the sulphur cross links is extremely difficult and not many devulcanisation techniques are available due to economical issues at present. Although Remould.org.uk are getting close.

Differences between Size Reduction, Reclaiming and Devulcanisation:

From the explanations above, the differences are clear.

Chemical Structures:

  • Size reduction has no effect on the chemical structure of the rubber.
  • Reclaiming rubber breaks bonds within the polymer chain (and a small amount of sulphur cross-links) and therefore has an effect on the polymer chain length.
  • Devulcanisation has a small amount of effect on polymer chain length but mostly gives large polymer chains which have no sulphur cross links.

Uses:

  • Size reduction is an additive/cheapener rather than a material for replacing rubber polymer in the rubber compound. The ratio of the original materials in the rubber compound would be the same. Larger, size reduced, rubber (rubber granules) can be used in horse arenas and playground surfaces.
  • Reclaim, unlike size reduction can be used to replace some rubber polymer being added in the rubber compound. In fact, if you really wanted, reclaim could make rubber compound by adding curatives/accelerators, although the quality would be poor.
  • Devulcanisation, similar to reclaim would be able to replace the rubber polymer. In fact, it would probably be able to replace nearly the entire rubber polymer and most of the compound!

Visual:

  • Size reduction of rubber produces, shred (for tyres only), granules and crumb.
  • Reclaim is extruded into blankets on a mill.
  • The best devulcanised rubber would be extruded and would be available like reclaim.

 

I hope this post will shed some light on the confusion between the two different types. If you have any questions feel free to leave a comment and I will get back to you ASAP.

 

Rubber Crumb / Granules

The process of making rubber goods produces a certain amount of waste. Some of this will be legitimate, such as flash, sprue, runners, etc, and some (almost inevitably) will be due to rejects and other problems. As long as the waste is cured (vulcanised) it can usually be recycled by size reduction into usable materials again. The ideal situation is when the producer segregates and saves the waste and it is then recycled and used back into their product.

The incoming waste is identified and checked and is then progressively broken down in size by passing it through very high energy cutters and granulators. The granulators have a removable, perforated “basket” as the base and this can be changed as required. The full range of sizes runs from 2.5 to 30mm. The common, usual sizes would be 4 or 6mm, and larger chunks would “whirl” around inside, passing through the cutters again and again, until they were small enough to fall through the basket. Vibrating sieve units separate or grade the output. High strength magnets are used at every possible flow point to ensure that any residual metal particles are removed. The product may need multiple passes and will then be bagged (25kg or “big bags”).

At this stage the material is known as “granules” and has a ready outlet in safety surfacing and the like.  It is used in the same way as the stone “chips” in tarmac. A typical specification would be 6 – 2 mm rubber granules – that means that no particle will be larger than 6mm and anything smaller than 2mm will have been removed (i.e. no dust) – that would be used as Base Layer for a surface. Another grade would be 4 – 1mm (on a similar basis) and would be used for the Top Coat  i.e. the visible surface. The sizes can be varied as required and the material used could be Tyre Rubber, EPDM, Nitrile etc. This type of material has a relatively low added value.

Rubber Crumb

This is where the real value of this type of recycling can be found.

The waste rubber is first granulated to about 4mm and then passed to a series of rotary grinding machines. Again, magnets are used at every possible place to remove any particles of residual metal (mainly from the original tyre construction). Once started, the process continues automatically – the powder is fed to sealed sieve units where the only exits are:

  • Correct sized material to the bagging units
  • Oversize material, which has not passed through the sieve, is automatically returned to the system and is reground until it is the correct size.

The actual sieves can readily be changed to make a wide range of particle sizes, and unlike some processes, our stated sieve size means the largest possible size the crumb can be – not the average.

Basic properties

In essence, the true basic properties of the material are the same as the properties of the waste material used to make the crumb or granules. However, the real properties that we are interested in are as follows:-

  1. A relatively inert material of known and controlled particle size (no oversize or dust)
  2. A material that is compatible with the type of rubber compound it is going back into.
  3. A material with a jagged, partially activated, very high surface area that will chemically bond into the rubber article when it is cured (vulcanised)  -   (crumb particles cannot be seen on the surface of the cured article, nor can they be “prised out” – crumb is used as an anti-tack dusted onto the surface of tyre sidewall veneer compound, that disappears completely when the tyre is cured).
  4. A material that is very cost effective, environmentally sound and technically viable

(Note: For very high tech applications (FKM etc) the compounder / producer can have peace of mind knowing that the only chemical materials in the crumb are exactly the same as in the product they are making – no compatibility or contamination issues.  That is of course, as long as they make use of our bespoke service, where they supply THEIR waste material, and we use it (and nothing else) to make THEIR own crumb.)

Why should you use it?

For the compounder:-

a)     The low initial cost and the possible value recovery aspects will make you popular

b)     The technical aspects can be extremely useful –

In small additions of 5 to 10 phr (parts per hundred of rubber)

  • It can reduce air trapping
  • It can reduce “laking” on the surface of “flat” mouldings
  • It can improve hot tear strength
  • It can reduce flow, or excessive “creep” in the uncured rubber

In larger additions – above 10 phr, to as much as you like – see i.

  • Physical properties will fall in relation to the amount of crumb added. If there are no physical requirements – cheap ladder feet, wheel barrow tyres, sleeping policemen  etc, over 50% of the total weight can easily be added.
  • As a cheap filler it is a low S.G., readily compatible blend of hydrocarbons and mineral material.  In very high additions it may be necessary to increase the amount of sulphur / accelerators slightly.

For the accountant:-

a)     It is low price material in the first place.  The word “cheap” conjurers up the wrong idea.

b)     Taken in conjunction with a robust system of internal waste collection and segregation – which is then passed onwards to the recycler – hopefully to be returned as “house” crumb – the economic advantage is completely maximised :-

  •  A useful, low cost raw material put back in stock
  •  Value recovery of internal waste and scrap
  •  Elimination of waste rubber disposal costs

How do you use it ?

Just like any other rubber filler.  If large amounts are used it will be better to add it after the addition of any oils, plasticisers or process aids.  It can have a tendency to absorb the oils resulting in slightly higher hardness than expected.