Rubber Reclaim Part 2

Although we’ve blogged about Rubber Reclaim in two previous posts (31/08/12 & 13/09/12), we thought another blog would reinforce Rubber Reclaim as a viable rubber hydrocarbon source, carbon black source and process aid.

In the 31/08/12 blog, which is still available to read, we wrote about how it is made, its basic properties and why a compounder should use it. In this post we hope to expand on these slightly and talk about ourselves, as UK and European suppliers of Reclaim.

How Rubber Reclaim is made:

Step 1) Collection and Selection of suitable materials

This is probably the most important step. In order to get a uniform and consistent product you have to use the correct materials. This is a part of the process that for many years has been overlooked hence producing inconsistent materials.

Step 2) Reduction in size and removal of contaminants.

In Tyre Reclaim this consists of removing the bead wire, cutting out the side wall then granulating the remaining materials to 2-4mm removing textile and metals.

In Butyl Reclaim Tubes are de-valved  and patches removed before being granulated.

Step 3) Blending

The rubbers are mixed with the chemicals required and the oils needed for the reclaiming process to take place.

All the chemicals and oils used today are REACH registered and compliant on PAH’s

Step 4) Cooking

This is where the materials are heated up. There are 2 main ways this is done either using an extruder to produce mechanical heat. Alternatively the materials are cooked in a digester using steam pressure to give 160° C

Step 5 ) Mastication

Either in the extruder or on a 2 roll mill the rubber is worked which breaks the polymer chain, also refining and blending the reclaim

Step 6) Filtering

The better quality producers at this point extrude the materials through a 60’s mesh (250 µm) filter to remove any undigested materials (nibs)

Step 7) Finishing

The filtered material is either extruded into blocks or is put back on a mill where a paper thin sheet is built up to 15mm thickness before being cut into blocks, coated in anti-tack agent and weighed off into the desired bundle weight (normally 25 kilos, but any bundle size is possible on request)

So why should you use Rubber Reclaim?

3 Reasons; RHC Source, Carbon Black Source and Processing Aid.

1) Rubber Hydrocarbon Source

Reclaim is a more cost effective source of rubber hydrocarbon than virgin rubber.

  • Attractive Price – Reclaim generally contains 50%+ RHC . For every 1% Reclaim you add you save 0.6% on Compound Cost*
  • Price Stability – Prices are not affected by NR and SBR prices.

* Based on an average compound cost of £1-70/kg

NR Prices versus Reclaim Prices

NR Prices versus Reclaim Prices

2) Carbon Black Source

  • Tyre reclaim contains approximately 27% of reinforcing Carbon Black
  • Easy to use as a Black Masterbatch
  • Much cleaner and easier to handle

3) Processing Aid

  • Improved Processing
  • Uniformity
  • Low Heat Development
  • Low Thermoplasticity
  • Minimum Reversion
  • Low Swelling and Shrinkage
  • High Rate of Cure
  • Good Aging
  • Good Shape Retention
  • Improved Tack

Other Savings include reduced mixing times and power consumption

Markets

There are 3 main types of rubber reclaim; tyre, butyl and EPDM. These reclaim serve a number of markets:

1) Tyre Reclaim

  •  Tyres- New
  • Retreading
  • General Moulding
  • Belting
  • Adhesives
  • Footwear
  • Sheeting/Matting

2) Butyl Reclaim

  • Inner Tubes
  • Tyre Lining
  • Tyre Repair
  • Cable Bedding Compound
  • Sound Reduction
  • Sheeting & Belting
  • Mastics and Adhesives

3) EPDM Reclaim

  • Automotive Extrusions
  • Hoses
  • Civil Engineering Extrusions
  • General Moulding
  • Roofing Membrane

Where do J. Allcock & Sons fit in?

J. Allcock & Sons are UK distributors of  Rubber Reclaim for GRP Limited, who are based in India and have a maximum capacity of 89,000MT’s per year.

We have been supplying reclaim from GRP Limited for many years and have proven it to be a successful partnership and have expanded our customer base overseas.

Although GRP Limited have distributors all over the world, any enquiries are welcome and if we cannot supply GRP Products to your location ourselves, we would happily point you in the right direction!

 

To conclude this post. Please do not hesitate in emailing ja@allcocks.co.uk  or phoning on +44 (0)161 223 7181 for any enquiries or information on reclaim. We firmly believe reclaim has a place in todays rubber compounding market.

 

Carnauba Wax

I haven’t written a technical blog recently, so I have decided that I should write one regarding Carnauba wax. We have high stocks of Type 3 Carnauba wax, in powder form, so perhaps it might bring us some new sales!

With the help of Norman Challinor, here is some information on Carnauba wax!

Carnuaba wax is also known as Brazil wax and Palm wax. It is a hard wax obtained from the leaves of the palm copernicia prunifera - a plant native to and only grown in north eastern Brazil.

It is usually in the form of hard yellow / brown flakes that can also be ground down to a fine powder and often offered in that alternative form.

Due to its fantastic properties compared to other waxes, most people believe it is one of the best waxes in the world; hence it is sometimes referred to as the “queen of waxes.”

It has a melting point of 80 – 86 oc and a density of about 0.97

The main components are:-

Aliphatic esters                                                   (40% by wt.)
Di-esters of 4 – hydroxycinnamic acid                (21% by wt.)
ω – hydroxycarboxylic acids                               (13% by wt.)
Fatty acid alcohols                                              (12% by wt.)

Predominantly derived from acids and alcohols in the c26 – c30  range.

Carnauba wax, can come in Type 1, Type 3 and Type 4. These “types” relate to the purifity level, with Type 1 being most pure and Type 4 being least.

It has a very wide range of uses, including …..

  • Polishes (Usually Type 4 used)
  • Food (chewing gum, gravy, sauces, sweets etc) (Usually Type 1 used)
  • Pharmaceutical (tablet coating agent)  (Usually Type 1 used)
  • Cosmetic (Usually Type 1 used)
  • And of course, as a process aid and mill / mould release agent in rubber compounds, particularly the harder to process specialist materials. (Usually Type 3 used)

For rubber compounders:

In rubbers, the hard nature of the material will not act as a softener but will behave as an internal lubricant, facilitating the incorporation and dispersion of the non-rubber ingredients.

Its relatively low melting point means that it will migrate to the surface of the rubber and form an extra, very thin, layer between the rubber surface and the metal it is in contact with – - i.e. The mill bowls or the mould surface.  The hardness of the wax means that it will not act as a sticky softener, but will form a release layer, overcoming the tendency for the rubber to stick to the metal.

Allcocks mostly sell, Type 3 Powder, and we really focus on selling to the high specification rubber compounding industry, such as FKM compounds.

Here is some technical information on our T3 Carnauba Wax Powder:

Solubility                                      Insoluble in water; partially soluble in Alcohol.
.                                                   Soluble on warming in Ethyl Acetate & Xylene.
Melting Point                               80-86°C
Acid Value                                   2-7 mg KOH/g
Sponification Value                     78-95 mg KOH/g
Ester Value                                 71-93 mg KOH/g
Sulphated ash                             No more than 0.25% w/w
Unsaponifiable matter                 50-55 μm
Particle Size                                100%  passing 600 μm
.                                                   94.8% passing 300 μm
                                                  88.1% passing 250 μm
                                                  40.6% passing 125 μm

If you have any questions regarding carnauba wax, please feel free to email ja@allcocks.co.uk! Despite only selling T3 Carnauba Wax powder, please feel free to get in touch regarding other types, we may be able to help.